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Thiol-ene emulsion step polymerization in a photochemical stirred tank reactor: Molecular weight, cyclization, and fragmentation

ABD

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Industry: Polymers
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Unlike many step polymerizations, the polymerization of bifunctional thiol and alkene monomers can be carried in emulsion to prepare a range of sulfur-containing polymer particles differing markedly from conventional emulsion chain polymers. This study examines how the change of polymerization mechanism affects polymer molecular weight, structure and composition. (318)
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